@article{heller_zambelli_1977,
title={Darstellung einiger Alkali- und Erdalkaliperoxoborate durch Perhydrolyse von Tris(methoxy)boran / Preparation of Some Peroxoborates of Alkaline and Alkaline Earth Metals by Perhydrolysis of Tris(methoxy)borane},
volume={32},
DOI={10.1515/znb-1977-1208},
abstractNote={Perhydrolysis of the trimethyl ester of boric acid with Η2O2/Η2Ο (85:15 by weight) in butanolic solvents in the presence of lithium- or cesium-tert-butylate in certain molar ratios yields Li2[B2(O2)2(OH)4 or Cs2[B2(O2)2(OH)4].
In methanol in the presence of MX2, where M = Ca, Sr or Ba and X = N-methylacetamide depending on the experimental conditions M[B2(O2)2(OH)4] · n CH3OH, M[B2(O2)2(OH)2(OOH)2] · CH3OH or a compound with a chain structure (anion C) are obtained. Perhydrolysis with H2O2/ H2O (98:2 by weight) yields Sr[B2(O2)2(OOH)4] · CH3OH, Ba[B2(O2)2(OOH)4] · CH3OH or Ba[B2(O2)2(OOH)4] · 2 H2O2.
Based on IR spectra and Raman spectra the structural features of these salts are discussed.},
number={12},
publisher={Walter de Gruyter GmbH},
author={Heller and Zambelli},
year={1977},
month={Dec}
}