Stoichiometric and catalytic Si–N bond formation using the p-block base Al(NMe2)3 release_q3ok35xntvdahe5tfhot2hpoty

by Lucy K. Allen, Raúl García-Rodríguez, Dominic S. Wright

Published in Dalton Transactions by Royal Society of Chemistry (RSC).

2015   Volume 44, Issue 27, p12112-12118


The aluminium reagent Al(NMe<sub>2</sub>)<sub>3</sub> acts as a stoichiometric or catalytic reagent in dehydrogenic Si–N bond formation using amines and silanes. The observed catalytic rate law suggests a mechanism involving the silane component in the deprotonation of the amine.
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Type  article-journal
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Year   2015
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DOI  10.1039/c5dt00662g
PubMed  25790240
Wikidata  Q54314346
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ISSN-L:  1477-9226
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