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Stoichiometric and catalytic Si–N bond formation using the p-block base Al(NMe2)3
release_q3ok35xntvdahe5tfhot2hpoty
by
Lucy K. Allen, Raúl García-Rodríguez, Dominic S. Wright
Published
in Dalton Transactions by Royal Society of Chemistry (RSC).
2015 Volume 44, Issue 27, p12112-12118
Abstract
The aluminium reagent Al(NMe<sub>2</sub>)<sub>3</sub> acts as a stoichiometric or catalytic reagent in dehydrogenic Si–N bond formation using amines and silanes. The observed catalytic rate law suggests a mechanism involving the silane component in the deprotonation of the amine.
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Crossref Metadata (via API)
Worldcat
SHERPA/RoMEO (journal policies)
wikidata.org
CORE.ac.uk
Semantic Scholar
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