Notizen: Homogene katalytische Hydrierung ungesättigter Carbonsäureester mit H2PtCl6 + SnCl2 in iso-Butanol / Homogeneous Catalytic Hydrogenation of Unsaturated Carboxylic Acid Esters with H2PtCl6 + SnCl2 in iso-Butanol release_nrzeet2qeff2zbndzp5q33q5py

by Walter Strohmeier, Luise Weigelt

Published in Zeitschrift für Naturforschung. B, A journal of chemical sciences by Walter de Gruyter GmbH.

Volume 32p597-598 (1977)

Abstract

The catalytical system, prepared from H<jats:sub>2</jats:sub>PtCl<jats:sub>6</jats:sub> + SnCl<jats:sub>2</jats:sub> · 2 H<jats:sub>2</jats:sub>O and the additives HBr and H<jats:sub>2</jats:sub>O in iso-butanol is very efficient for homogeneous hydrogenation of unsaturated esters under mild conditions. Reaction rates r up to 40 mMol · 1<jats:sup>-1</jats:sup> · min<jats:sup>-1</jats:sup> and turnover numbers UZ higher than 1.600 are observed.
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Type  article-journal
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Date   1977-05-01
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