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Oligomeric Supersandwich Structure of a Lithium Enamino- Cyclopentadienide
release_huafsqylzngslcrbww2uwald7e
by
Vasily V. Kotov, Gerald Kehr, Roland Fröhlich, Gerhard Erker
Published
in Zeitschrift für Naturforschung. B, A journal of chemical sciences by Walter de Gruyter GmbH.
2006 Volume 61, Issue 11, p1319-1322
Abstract
Deprotonation of 6-methyl-6-dimethylaminofulvene with a lithium amide base gave lithium (1-dimethylamino-ethenyl)cyclopentadienide. In the crystal it features a close to perfect oligomeric supersandwich structure. In contrast to related (aminomethyl-Cp)Li complexes here the enamino substituent is not directly involved in the formation of the oligomeric suprastructure.
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