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Persistent Radical Pairs Between N-Substituted Naphthalimide and Carbanion Exhibit pKa-Dependent UV-vis Absorption
release_awutg5rcirg2pcl7xlaushycsq
by
Xiancheng Nie, Tao Wang, Xiaoyu Chen, Wenhuan Huang, Linkun Huang, Biao Chen, Guoqing Zhang
Released
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by American Chemical Society (ACS).
2019
Abstract
A
new strategy is constructed for estimating and screening pK<sub>a</sub> values
among different carbon acids under ambient conditions via the UV-vis absorption
spectrum of persistent radical pair originating from an <i>N</i>-substituted naphthalimide (NNI) derivative in the presence of
various carbanions in organic solutions
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