Ceric-Cerium Oxidation of ortho-Cresol release_4bvzj7uqxzapxa2lnxrpmab56a

Abstract

F.M.H. Gujarati Science College, Indore Holkar Science College, Indore <em>Manuscript received 11 May 1982, revised 8 November 1982, accepted 19 March 1983</em> Ceric-cerium and <em>ortho-</em>cresol<em> </em>have been found to form an 1:1 complex with \(\lambda\)max at 449 mμ. The thermodynamic parameters of kinetics of the oxidation <em>have </em>been evaluated. The experimental findings are consistent with the postulate that the rate determining step in the reaction involves the disproportionation of a coordinate complex formed by the reactants, giving rise to products through free radical formation.
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