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Selective C–C coupling at a Pt(iv) centre: 100% preference for sp2–sp3 over sp3–sp3
release_25hkgyh7tzf3nbe4feeboiiek4
by
Paul A. Shaw, Jonathan Rourke
Published
in Dalton Transactions by Royal Society of Chemistry (RSC).
2017 Volume 46, Issue 14, p4768-4776
Abstract
Oxidative addition of alkyl halides to platinum(<sc>ii</sc>) gives six-coordinate platinum(<sc>iv</sc>) complexes that spontaneously reductively couple with complete selectivity.
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